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Season 1: Prophecy Girl

With the help of Angel, Giles discovers an ancient prophecy which foresees that Buffy will die if she fights The Master. Upon hearing of her doom, Buffy is met with the biggest decision of her young life.
When vampires attack a group of students at the school, Buffy decides to face her destiny. Unfortunately, the prophecy is deceiving and it is actually Buffy who frees the Master when he feeds on her and gains the power to break through the barrier.
Buffy falls unconscious into a pool of water and drowns but Xander and Angel arrive in time and Xander performs CPR to bring her back. Buffy wakes and is stronger after the encounter and the three head to the school to stop the Master, while the rest of the gang have their hands full fighting off the Hellmouth.

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Season 2: Becoming (Parts 1 and 2)

Angelus' origins from being vamped by Darla in 1753, vamping Drusilla in 1860, being cursed by the Gypsies in 1898, and meeting a demon named Whistler in New York in 1996 who shows him a better way of life are revealed while Angelus prepares to awaken Acathla, an ancient demon that will suck the Earth into the Demon Dimension.
Buffy and Willow find the spell to restore Angel's soul and Willow declares that she knows enough about magic to perform it. The gang almost come to blows when Xander tells Buffy outright that she doesn't care what happened to Ms Calendar, she only cares that she can get her boyfriend back. Kendra returns to Sunnydale because a dark power is rising and comes bearing a sword blessed by the knight who first slew Acathla.
Angelus tries to awaken the demon but fails. Needing someone to help him with the ritual, he distracts Buffy while Drusilla goes to collect Giles. Drusilla and her friends attack the rest of the gang but only Kendra is there to defend them, and the stakes are high.
After Drusilla's attack on her friends which resulted in the death of Kendra and Giles' abduction, Buffy is arrested for the murder but escapes from the police. She heads to the hospital where she learns that Xander has a broken arm and Willow is left in a coma. They all realise that Giles was taken by Drusilla and Buffy prepares herself to face Angelus. After being stopped by another cop, Spike comes to her aid and convinces her that he wants to be rid of Angelus too and they form an unusual alliance.
Buffy is forced to slay a vampire in front of her mother and tells her the truth but she does not want to accept it. When Buffy tries to leave to fight Angelus, Joyce tells her that if she goes she better not bother coming back. After retrieving Kendra's sword from the library she heads toward Angelus' mansion.
Meanwhile, Willow wakes up and decides to try the spell again and Xander runs to Buffy's aid. Drusilla uses her psychic powers to make Giles reveal the secret of the ritual to wake Acathla, and Angelus begins again. Buffy arrives and fights him while Spike takes Drusilla and leaves and Xander escapes with Giles. Acathla begins to awaken as Willow completes the spell and Angel returns.
Unfortunately it is too late and Buffy must send Angel to hell to stop Acathla's vortex. Devastated, Buffy returns home only to pack her bags and leaves Sunnydale on a bus.

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Season 3: Graduation Day (Parts 1 and 2)

The gang receive some valuable information from old enemy Anya who has actually witnessed an Ascension. She reveals that the Mayor plans to transform himself into pure demon, something that has not been seen for thousands of years. When Angel is poisoned by Faith to distract Buffy, Buffy faces Faith for the final time in order to get the only cure to the poison: Faith's blood.
After their ultimate 'Fight-to-the-Death' Faith escapes from Buffy, albeit in a coma, so Buffy offers her own blood to Angel to rid his body of the poison. When she recovers the gang finally devise a plan to defeat the Mayor, rallying the students and asking for their help in fighting the resulting serpent demon before Buffy leads him into the library which has been rigged with explosives.
 

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Season 4: Restless

Buffy, Xander, Giles and Willow sit down to watch videos after defeating Adam. They enter a bizarre dream world where they are pursued by a primitive force that they released via their enjoining spell. The force turns out to be the spirit of the first Slayer who speaks through Tara in their dream world and is confronting each of them with their deepest secrets and fears before killing them. Buffy eventually dispatches the primitive girl by ignoring her and they all wake up.
 

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Season 5: The Gift

Another imminent apocalypse is at hand in Sunnydale. Buffy must square off against a true God when Glory prepares to use Dawn to break down the walls between the dimensions and unleash all Hell on Earth but she needs Dawn's blood before her home dimension portal can be opened. Buffy, Xander, Willow, Giles, Anya, Tara and Spike go to battle with the knowledge that they may not all survive.

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Season 6: Two To Go/Grave

After exacting revenge on Warren for Tara's death, an extremely powerful and vengeful Willow now vows to go after the other two members of the trio, Jonathan and Andrew, forcing Buffy into the unlikely role of nerd-villain protector. After freeing the Duo from jail and escaping from Willow, the expanded group runs to the Magic Box to find a protection spell.
While all this is going on in Sunnydale, Spike undergoes a fierce challenge given by an African demon in order to become what he once was.
Willow, drained of her power, finds Rack and draws his energy into her, killing him in the process. At the Magic Box, Willow catches up to them all and takes on Buffy and Anya, who is doing her best to keep a magical barrier up around Willow. Buffy is no match for Willow's power, but eventually she is drained again and they escape while she is down.
Willow regains her strength and brings down Anya's barrier, tossing both her and Buffy aside. Willow heads out of the shop intent on completing her mission when an old friend magically appears in her way, willing to challenge her power....
Giles's new-found power brings Willow down momentarily and Giles magically binds her and leaves to catch up with Buffy. Willow telepathically controls Anya and gets her to break the binding spell. Willow draws Giles's energy into her and is hit by a sudden burst of emotion. Willow feels so much pain and hurt in the world and she decides to end it all.

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Season 7: Chosen

Buffy and Angel's reunion is interrupted by Caleb, who is ready for a final battle. The First Evil tells Buffy that it is everywhere and it will never die, but the Turok-Han will upset the balance, making it corporeal. Buffy conceives a plan that will turn the tables on The First.
 

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Source: TVTome.com